Tackifier resin refers to small molecule compounds that can improve the viscosity of rubber materials, especially surface viscosity. The following is a detailed explanation of the tackifier resin:
1. Characteristics and Classification
Tackifier resins typically have a relative molecular weight of several hundred to ten thousand and a high glass transition temperature. According to their sources and synthetic routes, they can be mainly divided into two categories: natural products and their derivatives, and synthetic resins.
1. Natural series resins: including rosin (such as rosin, tall pine resin, and wood pine resin), rosin derivatives (such as hydrogenated rosin, disproportionated rosin, polymerized rosin, esterified rosin, and maleated rosin), and terpene resins (such as alpha terpene resin, beta terpene resin, and terpene phenolic aldehyde resin).
2. Synthetic resin series: including polymer resins (such as C5, C9, and C5/C9 petroleum resins, dicyclopentadiene (DCPD) resins, Gumarone indene resins, styrene series resins) and condensation resins (such as alkylphenol formaldehyde resins, xylene resins).
2. Application and Function
Tackifier resin is mainly used as a modifier for polymers, widely used in adhesives, coatings, inks, as well as in rubber complexes, asphalt modifiers, and polyolefin modifiers. In the production process of rubber products and tires, tackifier resin is also an essential blending material. As a modifier for polymers, tackifier resins are mostly used as compounding agents to increase polymer adhesion, improve initial viscosity, and reduce operational or processing viscosity.
3. Mechanism of action
The mechanism of action of tackifier resin can be explained from two aspects:
1. Molecular adsorption and diffusion theory on rubber contact surfaces: When two materials come into contact, atoms and molecules in the materials will generate interaction forces, including strong forces such as chemical bonds, as well as weak forces such as hydrogen bonds and dispersion forces. For rubber materials, polymers can undergo diffusion and chain entanglement upon contact, and through the diffusion of polymer molecules, the two surfaces are ultimately connected together.
2. Formation theory of contact interface: The diffusion and entanglement of polymers are closely related to their relative molecular weight, and those with lower relative molecular weight are more prone to diffusion but have lower entanglement; When the relative molecular weight is high, diffusion is more difficult, but the strength after entanglement is better.
In summary, tackifier resin is an important chemical material with wide applications in multiple fields. Understanding the characteristics and classification of tackifier resins can help us better choose and use this material.